Summary
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1.
The effect of equiatomic amounts of sulfur, selenium, tellurium or phosphorus on the activity of a nonmixed WS2-catalyst in the hydrogenation of phenol under pressure has been compared.
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2.
When compared with sulfur, promoting by selenium more strongly changes the selectivity of the catalyst in the direction of an enhanced hydrogenation ability.
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3.
Tellurium and phosphorus lower the activity; meanwhile tellurium somewhat decreases and phosphorus increases the hydrogenation ability of a WS2-catalyst.
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S. M. Samoilov and A. M. Rubinshtein, Izv. AN SSSR, Otd. khim. n. 427 (1960).
S. M. Samoilov and A. M. Rubinshtein, Izv. AN SSSR, Otd. khim. n. 1158 (1957).
S. M. Samoilov and A. M. Rubinshtein, Izv. AN SSSR, Otd. khim. n. 1905 (1959).
Landolt-Bornstein, Bd. 1 (Atom und Molekularphysik) (Kristalle), 1955, p. 34.
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Samoilov, S.M. Investigation into the physical and chemical properties of WS2-catalysts. Russ Chem Bull 10, 1456–1457 (1961). https://doi.org/10.1007/BF00906131
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DOI: https://doi.org/10.1007/BF00906131