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The catalytic behavior of niobium pentoxide during vapor-phase amination of ethyl alcohol with aniline

  • A. A. Balandin
  • N. P. Sokolova
Article

Summary

  1. 1.

    Niobium pentoxide possesses catalytic activity in respect to the amination of ethyl alcohol with aniline. With a 1∶1 ratio of aniline to ethyl alcohol in the mixture which was passed the reaction tends mainly to the formation of N-ethylaniline. Change of aniline to alcohol ratio up to 1∶1.5 causes the amount of N, N-diethylaniline in the catalyzate to increase, the total extent of conversion remaining practically constant.

     
  2. 2.

    The most active of the catalysts which were studied proved to be powdered Nb2O5 obtained by burning the metal at 530° for one hour, i.e., the form of powdered Nb2O5 which was most active for dehyration of alcohols.

     

Keywords

Alcohol Ethyl Catalytic Activity Aniline Niobium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. A. Balandin, N. P. Egorova (Sokolova), Dokl. AN SSSR 57, 255 (1947).Google Scholar
  2. 2.
    A. A. Balandin, N. P. Sokolova, Izv. AN SSSR. Otd. Khim. n. 949 (1959).Google Scholar
  3. 3.
    F. V. Bel'chev, N. I. Shuikin, S. S. Novikov, Izv. AN SSSR. Otd. khim. n. 710 (1959).Google Scholar
  4. 4.
    F. V. Bel'chev, Tr. BSKhA26, No. 11, 87 (1958).Google Scholar
  5. 5.
    V. D. Sak, Tr. BSKhA31, 89 (1959).Google Scholar
  6. 6.
    N. S. Kozlov, N. I. Panova, Zh. obshch. khimii26, 2602 (1956).Google Scholar
  7. 7.
    H. Heinemann, R. W. Wert, W. S. W. McCarter, Industr. and Engng. Chem.41, 2928 (1949).Google Scholar
  8. 8.
    H. Noeske, H. Rolling, Germ. Fed. Rep. P. 949565, 20.IX. (1956).Google Scholar
  9. 9.
    U. S. P. 2609394 (1950).Google Scholar
  10. 10.
    Swiss P. 292409 (1953).Google Scholar
  11. 11.
    Kyu-hei Kobayashi, Motoyasu Mizushima, Wased applied Chem. Soc. Bull.14, No. 1 (30), 23 (1937).Google Scholar
  12. 12.
    T. H. Evans, A. N. Bourns, Canad. J. Technol.29, 1–18 (1951)Google Scholar
  13. 13.
    T. J. Deahl F. H. Stross, M. D. Taylor, U.S.P. 2580284, 25.XII. (1951)Google Scholar
  14. 14.
    A. G. Hill, J. H. Shipp, A. J. Hill, Industr. and Engng. Chem.43, 1579 (1951).Google Scholar
  15. 15.
    H. P. Hetzner, J. T. Rutherford, U.S. P. 2565428, 21, VIII. (1951).Google Scholar
  16. 16.
    A. V. Kikvidze, K. I. Areshidze, Zh. obshch. khimii23, 596 (1953).Google Scholar
  17. 17.
    C. Fuortes, S. Montagnani, Ann. Chim. (Rome)41, 515 (1951).Google Scholar
  18. 18.
    J. Pasek, V. Ruzicka, Statni ped. nakl. 243 (1957).Google Scholar
  19. 19.
    A. A. Balandin, N. I. Shuikin, F. T. Dymov, Zh. obshch. khimii,4, 1451 (1932).Google Scholar
  20. 20.
    G. P. 637730, November 6, 1936.Google Scholar
  21. 21.
    S. Chatterjee, M. Sanyal, M. Coswami, J. Indian Chem. Soc.15, 399 (1938).Google Scholar
  22. 22.
    U.S. P. 2515872, July 18, 1950.Google Scholar
  23. 23.
    M. Prostenik, Arhiv Kemi 22, 180 (1950)Google Scholar
  24. 24.
    M. B. Turova-Polyak, N. V. Borunova, E. S. Semenova, Zh. obshch. khimii23, 1024 (1953).Google Scholar
  25. 25.
    L. A. Munro, P. A. Washington, Canad. J. Chem.33, 1502, (1955).Google Scholar
  26. 26.
    A. A. Balandin, N. P. Sokolova, Izv. AN SSSR. Otd. khim. n. 398 (1960).Google Scholar
  27. 27.
    A. A. Balandin, N. P. Sokolova, Yu. P. Simanov, Izv. AN SSSR. Otd. khim. n. 415 (1961).Google Scholar
  28. 28.
    R. P. Lastovskii and Yu. I. Vainshtein, Applied Analysis in the Production of Intermediate Products and Dyes [in Russian] (Moscow, 1958).Google Scholar

Copyright information

© Consultants Bureau 1962

Authors and Affiliations

  • A. A. Balandin
    • 1
  • N. P. Sokolova
    • 1
  1. 1.N. D. Zelinskii Organic Chemistry InstituteAcademy of SciencesUSSR

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