Monatshefte für Chemie - Chemical Monthly

, Volume 109, Issue 6, pp 1321–1328 | Cite as

Aquotisierung descis-di-isothiocyanato-bis-äthylendiaminchrom(III)-Ions in sauren Lösungen Kinetik und Mechanismus der Substitutionsreaktionen von Komplexverbindungen, 53. Mitt.

  • Csaba Várhelyi
  • János Zsakó
  • Béla Gagyi
Anorganische, Struktur- und Physikalische Chemie
  • 16 Downloads

Aquation of the cis-di-isothiocyanato-bis-ethylenediamine-chromium(III)-ions in acidic solutions Kinetics and mechanism of substitution reactions of complexes, LIII

Abstract

The aquation rate ofcis-[Cr(en)2(NCS)2]NO3 has been studied at different temperatures and HClO4 concentrations. The protolytic pre-equilibrium (1) as well as the parallel aquation reactions (2) and (3) have been assumed. Activation enthalpy and entropy values have been derived from experimental data for both aquation reactions. By presupposing a dissociation mechanism, the activation parameters obtained as well as those of the aquation of thetrans isomer, are discussed in terms of the electronic structure. Equilibrium constants of reaction (1) are compared to those of the analogous Co(III) complexes and are discussed.

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Copyright information

© Springer-Verlag 1978

Authors and Affiliations

  • Csaba Várhelyi
    • 1
  • János Zsakó
    • 1
  • Béla Gagyi
    • 1
  1. 1.Chemische Fakultät“Babeş-Bolyai”-UniversitätCluj-NapocaRumänien

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