Conclusions
When spirocyclodienones, containing three- and five-membered rings, are treated with acid agents the cycloalkane portion of the molecule undergoes rupture with the formation of 4-substituted 2,6-dialkylphenols.
Literature cited
A. A. Volod'kin and V. V. Ershov, Izv. AN SSSR, Ser. Khim.,1962, 1293.
V. V. Ershov and A. A. Volod'kin, Izv. AN SSSR, Ser. Khim.,1963, 893.
G. A. Zlobina and V. V. Ershov, Izv. AN SSSR, Ser. Khim.,1964, 1666.
G. Chiurdoglu and B. Tursch, Bull. Soc. Chim. Belges,66, 600 (1957).
R. Ya. Levina, Yu. S. Shabarov, and V. K. Potapov, Zh. Obshch. Khimii,29, 3233 (1959).
N. M. Kizhner, Zh. Russ. Khim. Obshchestva,45, 955 (1913).
J. A. Marshall and N. Cohen, J. Am. Chem. Soc.,87, 2774 (1965).
C. L. Bumgardner, J. Organ. Chem.,29, 767 (1964).
W. Graham and G. Stone, Chem. and Ind.,1957, 1096.
V. V. Ershov and I. S. Belostotskaya, Izv. AN SSSR, Ser. Khim.,1965, 1301.
A. A. Volod'kin, G. D. Ostapets-Sveshnikova, and V. V. Ershov, Izv. AN SSSR, Ser. Khim.,1965, 2188.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 684–685, March, 1967.
The authors wish to thank N. E. Émanuel for his constant interest in the work during its execution.
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Belostotskaya, I.S., Volod'kina, V.I., Volod'kin, A.A. et al. Peculiarities of the dienone-phenol transformations of di-tert-butylspirocyclodienones under the influence of acid agents. Russ Chem Bull 16, 660–662 (1967). https://doi.org/10.1007/BF00906018
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DOI: https://doi.org/10.1007/BF00906018