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Reaction of diazomethane with triferrocenyl- and diferrocenyl(phenyl)carbonium salts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Triferrocenylchloromethane hydrochloride reacts with diazomethane to give triferrocenylethylene.

  2. 2.

    Triferrocenylethylene was reduced to 1,1,2 -triferrocenylethane and oxidized with potassium permanganate in alkaline medium.

  3. 3.

    Diferrocenyl (phenyl) chloromethane hydrochloride reacts with diazomethane to give a mixture of 1,2-diferrocenyl-1-phenylethylene and 1,1-diferrocenyl-2-phenylethylene.

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Literature cited

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva & Yu. A. Ustynyuk

Authors
  1. A. N. Nesmeyanov
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  2. É. G. Perevalova
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  3. L. I. Leont'eva
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  4. Yu. A. Ustynyuk
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 681–682, March, 1967.

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Nesmeyanov, A.N., Perevalova, É.G., Leont'eva, L.I. et al. Reaction of diazomethane with triferrocenyl- and diferrocenyl(phenyl)carbonium salts. Russ Chem Bull 16, 657–658 (1967). https://doi.org/10.1007/BF00906016

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  • DOI: https://doi.org/10.1007/BF00906016

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