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Synthesis and polarographic reduction of tetrahydrodioxodibenzoanthrylenetriptycene

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The following were produced for the first time: 12,13,14,15,9′,10′-hexahydro-12,15-dioxo-2,3∶6,7-dibenzo-13, 14∶9′,10′-anthrylenetriptycene (III) and 12,15,9′,10′-tetrahydro-12,15-dioxo-2,3∶6,7-dibenzo-13, 14∶9′,10′-anthrylenetriptycene (I).

  2. 2.

    The quinone (I) is polarographically reduced in dimethylformamide against a background of 0.1 N KNO3. The half-wave potentials of the first and second waves are equal to −630 and −1320 mV, respectively.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 568–570, March, 1967.

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Antik, L.V., Mamedzade, R.Y., Klabunovskii, E.I. et al. Synthesis and polarographic reduction of tetrahydrodioxodibenzoanthrylenetriptycene. Russ Chem Bull 16, 548–550 (1967). https://doi.org/10.1007/BF00905989

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  • DOI: https://doi.org/10.1007/BF00905989

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