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Kinetics of the decomposition of 3,3-dinitrobutanol-2 in water under the action of bases

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The decomposition of 3,3-dinitrobutanol-2 in water was studied at 25° and ionic strength of the solution 0.1.

  2. 2.

    The equilibrium constant of the decomposition of 3,3-dintrobutanol-2 into acetaldehyde and dinitro-ethane was determined.

  3. 3.

    The second-order rate constant of the interaction of acetaldehyde and the dinitroethane anion was determined.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    Yu. N. Belokon' & V. M. Belikov

Authors
  1. Yu. N. Belokon'
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  2. V. M. Belikov
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Additional information

The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR, of July 12, 1962, as the dissertation work of Yu. N. Belokon'.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 528–532, March, 1967.

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Belokon', Y.N., Belikov, V.M. Kinetics of the decomposition of 3,3-dinitrobutanol-2 in water under the action of bases. Russ Chem Bull 16, 512–515 (1967). https://doi.org/10.1007/BF00905982

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  • DOI: https://doi.org/10.1007/BF00905982

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