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Free-radical addition of primary alcohols toα-olefins

  • G. I. Nikishin
  • V. D. Vorob'ev
  • A. D. Petrov
Inorganic and Analytical Chemistry
  • 24 Downloads

Summary

  1. 1.

    The synthesis of a series of secondary alcohols has been carried out by the addition of C5–C10 primary alcohols to C6 – C13 α-olefins. The reaction initiator was t-butyl peroxide.

     
  2. 2.

    The optimum conditions for this reaction are: temperature, 140– 160°; time, 3–6 hours; molar ratio alcohol: olefin: peroxide=20 ∶ 1 ∶ 0.3.

     

Keywords

Alcohol Peroxide Optimum Condition Primary Alcohol Secondary Alcohol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    W. H. Urry, F. W. Stacey, E. S. Huyser, and O. O. Juveland, J. Amer. Chem. Soc.76, 450 (1954).Google Scholar
  2. 2.
    F. Breusch and S. Sokulla, Ber.86, 678 (1953).Google Scholar
  3. 3.
    E. E. Drever, G. I. Keim, G. D. Mites, U. Shedlovsky, and J. Ross, Industr. and Engng Chem.36, 610 (1944).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1961

Authors and Affiliations

  • G. I. Nikishin
    • 1
  • V. D. Vorob'ev
    • 1
  • A. D. Petrov
    • 1
  1. 1.The N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRUSSR

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