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Imides of acids of phosphorus

Communication 6. Trialkyl-n-acyl imidophosphates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By reactions of dialkyl chlorophosphates and methane sulfonyl chloride with sodium azide in aqueous solution, azides of dialkyl phosphoric acids and methane sulfonic acid were obtained.

  2. 2.

    By reactions of triethyl phosphite with diethyl azidophosphate and methane sulfazide, triethyl-N-diethyl phosphoryl imidophosphate and triethyl-N-methane sulfonyl imidophosphate were obtained; with hydrogen chloride these compounds give diethyl-N-diethyl phosphoryl aminophosphate and diethyl-N-methane sulfonyl aminophosphate.

  3. 3.

    It was shown that the P=N bond in the N-acyl imidophosphates investigated is resistant to the action of water, alkylating agents, carbon bisulfide and chlorine.

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Literature cited

  1. M. I. Kabachnik and V. A. Gilyarov, Izvestiya Akad. Nauk. Otd. khim. n., 1956, 790

  2. M. I. Kabachnik, V. A. Gilyarov and E. N. Tsvetkov, Izvestiya Akad. Nauk SSSR. Otd. khim. n.,1959, 2135.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    M. I. Kabachnik & V. A. Gilyarov

Authors
  1. M. I. Kabachnik
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  2. V. A. Gilyarov
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Kabachnik, M.I., Gilyarov, V.A. Imides of acids of phosphorus. Russ Chem Bull 10, 758–761 (1961). https://doi.org/10.1007/BF00905941

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  • DOI: https://doi.org/10.1007/BF00905941

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