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Synthesis of β-carboranylacrylic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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A method is presented for synthesis ofβ-carboranylacrylic acids by hydrolysis with concentrated sulfuric acid of 1, 1-dichloro-3-ethoxy-3-carboranyl-1-propenes, which are obtained from carboranyllithiums and 1, 1, 3-trichloro-3-ethoxy-1-propene.

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Literature cited

  1. L. I. Zakharkin, A. I. L'vov, and A. V. Grebennikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2282 (1968).

  2. A. N. Nesmeyanov, R. Kh. Freidlina, and L. I. Zakharkin, Dokl, Akad. Nauk SSSR,97, 91 (1954).

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  3. L. I. Zakharkin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 314 (1956).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2041–2043, September, 1969.

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Zakharkin, L.I., Kazantsev, A.V. & Litovchenko, L.E. Synthesis of β-carboranylacrylic acids. Russ Chem Bull 18, 1892–1893 (1969). https://doi.org/10.1007/BF00905834

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  • DOI: https://doi.org/10.1007/BF00905834

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