Conclusions
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1.
The hydrochlorination of β-silicon-containing vinyl ethers was investigated and it was shown that at a temperature below 30°, the reaction proceeds with the formation of β -silicon-containing α-chloroethyl ethers.
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2.
In contrast to the sulfur analogues, the β-silicon-containing vinyl sulfides, at a temperature above -15° and an excess of hydrogen chloride, the formation of β -silicon-containing α-chloro ethers is complicated by their cleavage at the Si-C bond. A reaction scheme is presented.
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Literature cited
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M. F. Shostakovskii, N. V. Komarov, and N. N. Vlasova, Zh. Obshch. Khim.,37, 1151 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 914–916, April, 1968.
GLC analysis was carried out by V. V. Keiko, to whom the authors express their gratitude.
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Shostakovskii, M.F., Komarov, N.V., Tsykhanskaya, I.I. et al. The hydrochlorination reaction of β-silicon-containing vinyl ethers. Russ Chem Bull 17, 877–879 (1968). https://doi.org/10.1007/BF00905776
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DOI: https://doi.org/10.1007/BF00905776