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Reactions of diisobutyl- and diethylaluminum hydrides with α-acetylenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

To obtain Al vinyl compounds R2A1CH=CHR' by reacting R2AlH with HC=CR', we must use weakly acid acetylenes (alkyl acetylenes) and perform the reaction in aliphatic hydrocarbons at a low temperature in excess acetylene.

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Literature cited

  1. L. I. Zakharkin, V. V. Gavrilenko, and L. L. Ivanov, Zh. Obshch. Khim.,37, 992 (1967).

    Google Scholar 

  2. G. Wilke and H. Müller, Liebigs Ann. Chem.,629, 222 (1960).

    Google Scholar 

  3. T. R. Surtees, Austral. J. Chem.,18, No. 1, 14 (1965).

    Google Scholar 

  4. V. V. Markova, V. A. Kormer, and A. A. Petrov, Zh. Obshch. Khim.,37, 226 (1967).

    Google Scholar 

  5. P. S. Skell and P. K. Freeman, J. Organ. Chem.,29, 2524 (1964).

    Google Scholar 

  6. P. Binger, Angew. Chemie,75, 918 (1963).

    Google Scholar 

  7. H. Gilman and G. L. Schwebke, J. Organometal. Chem.,4, 485 (1965).

    Google Scholar 

  8. L. I. Zakharkin, O. Yu. Okhlobystin, and K. A. Bilevich, J. Organometal. Chem.,2, 309 (1964).

    Google Scholar 

  9. L. L. Ivanov, V. V. Gavrilenko, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1989 (1964).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    V. V. Gavrilenko, B. A. Palei & L. I. Zakharkin

Authors
  1. V. V. Gavrilenko
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  2. B. A. Palei
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  3. L. I. Zakharkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–912, April, 1968.

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Gavrilenko, V.V., Palei, B.A. & Zakharkin, L.I. Reactions of diisobutyl- and diethylaluminum hydrides with α-acetylenes. Russ Chem Bull 17, 872–874 (1968). https://doi.org/10.1007/BF00905774

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  • DOI: https://doi.org/10.1007/BF00905774

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