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Synthesis and some properties of fluorine-containing ketone derivatives of cyclopentadienylmanganesetricarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The fluorine-containing ketones of cyclopentadienylmanganesetricarbonyl, (CO)3MnC5H4COCF3 and (CO)3MnC5H4COC3F7, were synthesized and characterized by their IR and PMR spectra.

  2. 2.

    The following reactions of (CO)3MnC5H4COCF3 were studied: the fluoroform reaction, reduction with lithium aluminum hydride, and reaction with Grignard reagents.

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Literature cited

  1. R. Riemschneider and K. Petzoldt, Z. Naturforsch.,15b, 627 (1960).

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  2. A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and I. B. Zlotina, Dokl. Akad. Nauk SSSR,154, 391 (1964).

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  3. A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and G. K. I. Magomedov, Dokl. Akad. Nauk SSSR,158, 163 (1964).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova & I. B. Zlotina

Authors
  1. A. N. Nesmeyanov
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  2. K. N. Anisimov
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  3. N. E. Kolobova
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  4. I. B. Zlotina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 901–902, April, 1968.

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Nesmeyanov, A.N., Anisimov, K.N., Kolobova, N.E. et al. Synthesis and some properties of fluorine-containing ketone derivatives of cyclopentadienylmanganesetricarbonyl. Russ Chem Bull 17, 861–862 (1968). https://doi.org/10.1007/BF00905770

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  • DOI: https://doi.org/10.1007/BF00905770

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