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Action of bromine and chlorine on cyclopentadienylmanganesetricarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Equimolar quantities of bromine and acetylcyclopentadienemanganesetricarbonyl (CMT) react to form α-bromoacetyl-CMT.

  2. 2.

    Five functional derivatives of α-bromoacetyl-CMT were synthesized.

  3. 3.

    Chlorination of CMT and acetyl-CMT leads to disruption of the ferrocene structure to form, among other decomposition products, a chloride of the composition [Mn(CO)4]2Cl2.

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Literature cited

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Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova & I. B. Zlotina

Authors
  1. A. N. Nesmeyanov
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  2. K. N. Anisimov
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  3. N. E. Kolobova
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  4. I. B. Zlotina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 898–901, April, 1968.

The authors convey their gratitude to B. V. Loshkin for taking and discussing the IR-spectra.

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Nesmeyanov, A.N., Anisimov, K.N., Kolobova, N.E. et al. Action of bromine and chlorine on cyclopentadienylmanganesetricarbonyl. Russ Chem Bull 17, 858–860 (1968). https://doi.org/10.1007/BF00905769

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  • DOI: https://doi.org/10.1007/BF00905769

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