Conclusions
Hither esters of malonic acid have been prepared in good yield by transesterification of lower esters with appropriate primary or secondary alcohols in the presence of alkaline or acid catalysts.
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Literature cited
L. S. Bondar' and R. A. Okunev, Izv. Akad. Nauk SSSR, Ser. Khim. 1965, 1196.
W. Kymel and C. A. Cope, J. Am. Chem. Soc.65, 1992 (1943).
A. R. Bader and M. A. Vogel, J. Am. Chem. Soc.74, 59 (1952).
K. Kulka, U. S. Patent 3,075,892 (1963); Chem. Abstracts59, 6194d (1963).
G. P. Kugatova-Shemyakina and D. A. Kazlauskas, Izv. Akad. Nauk SSSR, Ser. Khim. 1966, 511.
R. K. Kudryavtsev, Zh. Obshch. Khim.27, 1686 (1957).
G. Baker, Introduction to the Electronic Theory of Organic Reactions [Russian translation],“Mir” Press, 1965, 0. 257.
G. Baker, Introduction to the Electronic Theory of Organic Reactions [Russian translation],“Mir” press, p. 253.
M. Bender, Mechanism of Catalysis of Nucleophilic Reactions of Carboxylic Acid Derivatives [Russian translation],“Mir” press, 1965, p. 62.
H. Serwy, Bull. Soc. Chim. Beiges42, 483 (1933).
M. H. Palomaa and J. Mikkila, Ber.75, 1659 (1952).
L. S. Bondar', R. A. Okunev, P. P. Rodionov, and N. V. Pylina, Izv. Akad Nauk SSSR, Ser. Khim.1965, 1893.
Timmermans, Bull. Soc. Chim. Beiges36, 506 (1927).
H. J. Backer and J. Lolkema, Recueil trav. chim.57II, 1234 (1938).
H. P. Gallus and A. K. MacBeth, J. Chem. Soc.1937, 1181.
R. L. Frank, W. R. Davis, Jr., S. S. Drake, and J. R. McPherson, Jr., J. Am. Chem. Soc.66, 1509 (1955).
H. Staudinger and H. Schwalenstocker, Ber. 68, 727 (1935).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 892–895 (1968).
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Bondar', L.S., Rodionov, P.P. & Okunev, R.A. Transesteeification of malonic esters. Russ Chem Bull 17, 851–854 (1968). https://doi.org/10.1007/BF00905767
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DOI: https://doi.org/10.1007/BF00905767