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Interaction of ethyleneamides and the dialkylamides of glycolphosphorous acids with chloral

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The di-β-chloroethylamide of ethyleneglycolphosphorous acid has been prepared.

  2. 2.

    When chloral reacts with the ethyleneamides and dialkylamides of glycolphosphorous acids a Perkov rearrangement occurs with opening of the phospholane and phosphorinane rings, and the ethyleneimine ring in the case of ethyleneamides remains without change attached to the phosphorous atom. The structure of the compounds obtained is confirmed by infrared spectra.

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Author information

Authors and Affiliations

  1. A. E. Arbusov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    N. P. Grechkin, R. R. Shagidullin & L. N. Grishina

Authors
  1. N. P. Grechkin
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  2. R. R. Shagidullin
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  3. L. N. Grishina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 854–859, April, 1968.

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Grechkin, N.P., Shagidullin, R.R. & Grishina, L.N. Interaction of ethyleneamides and the dialkylamides of glycolphosphorous acids with chloral. Russ Chem Bull 17, 817–820 (1968). https://doi.org/10.1007/BF00905761

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  • DOI: https://doi.org/10.1007/BF00905761

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