Skip to main content
SpringerLink
Log in

Alkylating properties of alkyl perfluoroisobutenyl ethers

Communication 1. Complexes of alkyl perfluoroisobutenyl ethers with trialkylamines

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The alkylating ability of the alkyl perfluoroisobutenyl ethers was demonstrated.

  2. 2.

    The reaction of these ethers with tertiary amines gave complexes, which contained the tetraalkylammonium cation and the mesomeric anion of perfluoro-1-isobuten-l-ol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. I. L. Knunyants, S. T. Kocharyan, Yu. A. Cheburkov, M. D. Bargamova, and E. M. Rokhlin, Dokl. Akad. Nauk SSSR,165, 827 (1965).

    Google Scholar 

  2. S. T. Kocharyan, E. M. Rokhlin, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1847.

  3. S. T. Kocharyan, E. M. Rokhlin, Yu. A. Cheburkov, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1966, 1870.

  4. S. T. Kocharyan, E. M. Rokhlin, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1849.

  5. S. T. Kocharyan, P. V. Petrovskii, E. M. Rokhlin, Yu. A. Cheburkov, E. I. Fedin, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1342.

  6. I. L. Knunyants, Yu. A. Cheburkov, and M. D. Bargamova, Izv. Akad. Nauk SSSR, Ser. Khim.,1963, 1393.

  7. Yu. A. Cheburkov, M. D. Bargamova, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1964, 367.

  8. Yu. A. Cheburkov, N. Mukhamadaliev, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim,1965, 1476.

  9. I. L. Knunyants, Yu. A. Cheburkov, and M. D. Bargamova, Izv. Akad. Nauk SSSR, Ser. Khim.,1966, 1048.

  10. Yu. A. Cheburkov, Yu. A. Aronov, P. V. Petrovskii, N. N. Shapet'ko, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1395.

  11. Yu. A. Cheburkov, Dissertation [in Russian], Moscow (1967).

  12. I. L. Knunyants, Yu. A. Cheburkov, M. A. Bargamova, E. I. Fedin, and P. V. Petrovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1966, 1031.

  13. Yu. A. Cheburkov, M. D. Bargamova, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 2124.

  14. D. C. England and C. G. Krespan, J. Am. Chem. Soc.,88, 5582 (1966).

    Google Scholar 

  15. S. M. Shein and V. A. Ignatov, Zh. Obshch. Khim.,33, 2645, 2667 (1963).

    Google Scholar 

  16. S. M. Shein and A. D. Khmelinskaya, Izv. Sibirsk. Otd. Akad. Nauk SSSR, Ser. Khim.,1966, No. 2, 89.

    Google Scholar 

  17. S. M. Shein and M. I. Krasnosel'skaya, Zh. Obshch. Khim.,36, 2148 (1966).

    Google Scholar 

  18. J. Burdon, W. B. Hollyhead, and J. C. Tatlow, J. Chem. Soc.,1965, 5152.

  19. L. A. Wall, W. P. Pummer, J. E. Fearn, and J. M. Antonucci, J. Res. Nat. Bur. Std.,67A, 481 (1963).

    Google Scholar 

  20. E. J. Forbes, R. D. Richardson, M. Stacey, and J. C. Tatlow, J. Chem. Soc.,1959, 2019.

  21. I. L. Knunyants, L. S. German, and B. L. Dyatkin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1965, 1353.

  22. W. Lossen, Liebigs Ann. Chem.,181, 374 (1876).

    Google Scholar 

  23. I. L. Knunyants, L. S. German, and B. L. Dyatkin, Izv. Akad. Nauk SSSR, Otd. Khim. Nau,1961, 1513.

  24. Yu. A. Cheburkov and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1963, 1573.

  25. German Patent 1,191,813 (1965); C. A.,63, 14909d (1965).

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    S. T. Kocharyan, E. M. Rokhlin & I. L. Knunyants

Authors
  1. S. T. Kocharyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. M. Rokhlin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. L. Knunyants
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp, 846–854, April, 1968.

This paper is published on the basis of the decision made by the Board of Chief Editors of the journals of the Academy of Sciences of the USSR on July 12, 1962 as the dissertational work of S. T. Kocharyan.

The authors are deeply indepted to I. D. Rubin, who recorded the NMR spectra, and to P. V. Petrovskii, who interpreted them.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kocharyan, S.T., Rokhlin, E.M. & Knunyants, I.L. Alkylating properties of alkyl perfluoroisobutenyl ethers. Russ Chem Bull 17, 810–816 (1968). https://doi.org/10.1007/BF00905760

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00905760

Keywords

Search

Navigation