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Addition of hydrochlorosilanes to diallyl esters of dicarboxylic acids

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The products of addition to one double bond of the ester were obtained by the addition of trichlorosilane, methyldichlorosilane and dimethylchlorosilane to the diallyl esters of succinic, adipic and terephthalic acid, and the corresponding methoxysilanes were isolated.

  2. 2.

    The yield of the adducts increases in the order: HSiCl3 < CH3SiHCl3 < (CH3)2SiHCl.

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Literature cited

  1. T. I. Chernysheva, N. S. Nametkin, and P. L. Grinberg, Collection“Synthesis and Properties of Monomers” [in Russian], “Nauka” (1964), p. 135.

  2. R. Calas, N. Duffaut, and V. Ducas, Rev. Franc. Corps Gras,1, 387 (1954); C. A.,49, 10854i (1955).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 832–835. April, 1968.

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Andrianov, K.A., Makarova, L.I. & Zima, T.A. Addition of hydrochlorosilanes to diallyl esters of dicarboxylic acids. Russ Chem Bull 17, 797–799 (1968). https://doi.org/10.1007/BF00905756

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  • DOI: https://doi.org/10.1007/BF00905756

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