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Cohydrolysis reaction of phenyldichlorosilane with triethylchlorosilane and dialkyl(aryl)dichlorosilanes

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the cohydrolysis reaction of phenyldichlorosilane with triethylchlorosilane and dialkyl(aryl)dichlorosilanes. The reaction proceeds with the formation of cohydrolysis products and the products of separate hydrolysis.

  2. 2.

    The cohydrolysis of dialkyl(aryl)dichlorosilanes with phenyldichlorosilane gives up to 73% of distillable cyclic compounds and undistillable oligomers.

  3. 3.

    The cohydrolysis of phenyldichlorosilane with triethylchlorosilane led to the isolation of some new phenylhydrosiloxanes with triethylsilyl end groups of general formula (C2H5)3Si[O-Si(C6H5)H]n-OSi(C2H5 3, where n=1–4, while the cohydrolysis of phenyldichlorosilane with dialkyl(aryI)dichlorosilanes led to the isolation of seven new cyclic alkylarylcyclosiloxanes.

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Literature cited

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  4. V. Bazant, V. Chvalovsky, and J. Rathousky, Organosilicon Compounds, Prague (1965).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow Institute of Fine Chemical Technology and Tbilissk State University, USSR

    K. A. Andrianov, A. I. Nogaideli, L. M. Khananashvili & L. I. Nakaidze

Authors
  1. K. A. Andrianov
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  2. A. I. Nogaideli
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  3. L. M. Khananashvili
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  4. L. I. Nakaidze
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 828–832, April, 1968.

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Andrianov, K.A., Nogaideli, A.I., Khananashvili, L.M. et al. Cohydrolysis reaction of phenyldichlorosilane with triethylchlorosilane and dialkyl(aryl)dichlorosilanes. Russ Chem Bull 17, 793–796 (1968). https://doi.org/10.1007/BF00905755

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  • DOI: https://doi.org/10.1007/BF00905755

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