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Synthesis and properties of cyclopentadienyl compounds of hafnium

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dihafniumoxane π-cyclopentadienyl compounds of the type: a) R2(C5H5)HfOHf(C5H5)R2 (R is a chelate residue of acetylacetone or 8-oxyquinoline); b) Br(C5H5)2HfOHf(C5H5)2Br, were produced.

  2. 2.

    π-Cyelopentadienyl, chelate compounds of hafnium containing anionic groups: C5H6HfR2X, X= Cl, Br, ONO2 were synthesized.

  3. 3.

    The IR spectra of π-cyclopentadienyl compounds of hafnium were measured and discussed.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    É. M. Brainina, M. Kh. Minacheva & B. V. Lokshin

Authors
  1. É. M. Brainina
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  2. M. Kh. Minacheva
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  3. B. V. Lokshin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 817–823, April, 1968.

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Brainina, É.M., Minacheva, M.K. & Lokshin, B.V. Synthesis and properties of cyclopentadienyl compounds of hafnium. Russ Chem Bull 17, 784–789 (1968). https://doi.org/10.1007/BF00905753

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  • DOI: https://doi.org/10.1007/BF00905753

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