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Mass spectrometry of steroid systems

Communication 14. Determination of the configuration of model monocyclic alcohols of the tert-butyl-cyclohexanol series

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The mass spectra of epimeric secondary and tertiary alcohols of the series of 3-tert-butyl-4-methoxy-cyclohexanol was studied. The alcohols in the cis-l, 4-OH/H configuration are considerably more easily dehydrated under electron impact than their trans-1, 4-OH/H epimers.

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Literature cited

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Authors and Affiliations

  1. Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR, USSR

    V. S. Bul'fson, V. I. Zaretskii, V. G. Zaikin, A. A. Akhrem, A. V. Kamernitskii & A. M. Prokhoda

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. S. Bul'fson, V. I. Zaretskii, V. G. Zaikin, A. A. Akhrem, A. V. Kamernitskii & A. M. Prokhoda

Authors
  1. V. S. Bul'fson
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  2. V. I. Zaretskii
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  3. V. G. Zaikin
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  4. A. A. Akhrem
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  5. A. V. Kamernitskii
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  6. A. M. Prokhoda
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 801–807, April, 1968.

For Communication 13 of this series, see [1].

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Bul'fson, V.S., Zaretskii, V.I., Zaikin, V.G. et al. Mass spectrometry of steroid systems. Russ Chem Bull 17, 770–775 (1968). https://doi.org/10.1007/BF00905750

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  • DOI: https://doi.org/10.1007/BF00905750

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