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Investigation of the conversions of cyclohexene in the presence of nickel on carriers

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The vapor-phase conversion of cyclohexene under mild conditions (90–140°) was studied.

  2. 2.

    On all the catalysts tested (in an atmosphere of nitrogen), disporportionation of the cycloolefin was accompanied by dehydrogenation reactions: the ratio C6H6/C6H12 > 0.5 and increased with increasing temperature.

  3. 3.

    Catalysts Ni-A12O3 and Ni-zeolite NaX showed high activity and good stability; Ni-ZnO was less active and was rapidly deactivated.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    N. V. Borunova, I. E. Neimark, L. Kh. Freidlin, I. L. Popova & V. G. Il'in

  2. Institute of Physical Chemistry, Academy of Sciences of the UkrSSR, USSR

    N. V. Borunova, I. E. Neimark, L. Kh. Freidlin, I. L. Popova & V. G. Il'in

Authors
  1. N. V. Borunova
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  2. I. E. Neimark
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  3. L. Kh. Freidlin
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  4. I. L. Popova
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  5. V. G. Il'in
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 773–776, April, 1968.

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Borunova, N.V., Neimark, I.E., Freidlin, L.K. et al. Investigation of the conversions of cyclohexene in the presence of nickel on carriers. Russ Chem Bull 17, 745–748 (1968). https://doi.org/10.1007/BF00905744

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  • DOI: https://doi.org/10.1007/BF00905744

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