Conclusions
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1.
The IR, NMR, UV, and Raman spectra of arylhydrazones ofω-methylglyoxal and diketobutyric acid were taken and discussed.
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2.
All the products considered possessed a hydrazone structure.
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3.
Arylhydrazones ofω-methylglyoxal are inclined to form intermolecular hydrogen bonds, while derivatives of diketobutyric acid in solutions represent a mixture of approximately equal amounts of the isomers with intramolecular hydrogen bonds formed by the hydrazone protons with the ketone and ester groups.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 729–735, April, 1968.
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Kitaev, Y.P., Nivorozhkin, L.E., Titova, Z.S. et al. Study of the structure and reactivity of nitrogen-containing derivatives of carbonyl compounds. Russ Chem Bull 17, 705–710 (1968). https://doi.org/10.1007/BF00905736
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DOI: https://doi.org/10.1007/BF00905736