Skip to main content
SpringerLink
Log in

Röntgenstrukturanalyse des Methyl-5-acetylamino-7,8-anhydro-4,9-bis-O-(t-butyldimethylsilyl)-3,5-didesoxy-L-glycero-β-D-galakto-2-nonulopyranosidon-säuremethylesters

X-ray crystal structure analysis of the methyl-5-acetylamino-7,8-anhydro-4,9-bis-O-(t-butyldimethylsilyl)-3,5-didesoxy-L-glycero-β-D-galacto-2-nonulopyranosidonic acid methyl ester

  • Anorganische und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

An X-ray crystal structure analysis of the title compound was carried out at −168°C in order to assign the stereochemistry around the oxirane: C25H49NO8Si2, trigonal, R3,a=25.18(1),c=13.55(1) Å (hexagonal axes),Z=9,d x =1.105.

The structure was solved with direct methods and refined to anR-factor of 0.086.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Brandstetter, H. H., Zbiral, E., Helv. Chim. Acta61, 1832 (1978).

    Google Scholar 

  2. Brandstetter, H. H., Zbiral, E., Helv. Chim. Acta63, 327 (1980).

    Google Scholar 

  3. Mark, E., Zbiral, E., Brandstetter, H. H., Mh. Chem.111, 289 (1980).

    Google Scholar 

  4. Mark, E., Zbiral, E., Mh. Chem.112, 215 (1981).

    Google Scholar 

  5. Schauer, R., Angew. Chem.85, 128 (1973).

    Google Scholar 

  6. Sandhoff, K., Angew. Chem.89, 283 (1977).

    Google Scholar 

  7. Heide, H., Schwick, H. G., Angew. Chem.85, 803 (1973).

    Google Scholar 

  8. Jeanloz, R. W., Codrington, J. F., in: Biological Roles of Sialic acidRosenberg, A., Schengrund, C. L., Hrsg.), S. 201–238. New York: Plenum Press. 1976;

    Google Scholar 

  9. Jäckh, R., Chemie in unserer Zeit10, 139 (1976).

    Google Scholar 

  10. Weiss, L., Guest Editorial, J. Nat. Canc. Inst.50, 3–19 (1973).

    Google Scholar 

  11. Suttajit, M., Winzler, R. J., J. Biol. Chem.246, 3398 (1971);

    Google Scholar 

  12. Suttajit, M., Reichert, M., Winzler, R. J., ibid246, 3405 (1971).

    Google Scholar 

  13. Kraska, B., Schifferdecker, B., Veith, H. J., in: Glyconjugates, S. 79, Proc. Fifth Int. Symp. 1979 (Schauer, R., Buddecke, E., Kramer, M. F., Vliegenthart, J. F. G., Wiegandt, H., Hrsg.). Stuttgart: G. Thieme.

  14. Meindl, P., Tuppy, H., Hoppe-Seyler's Z. physiol. Ch.350, 1088 (1969);

    Google Scholar 

  15. Meindl, P., Tuppy, H., Mh. Chem.100, 1295 (1969).

    Google Scholar 

  16. Tuppy, H., Gottschalk, A., in: Glycoproteins (Gottschalk, A., Hrsg.). (BBA Library.) Elsevier. 1972.

  17. C. A.82, 140408g (1975);

  18. Brossmer, R., Burk, G., Eschenfelder, V., Holmquist, L., Jäckh, R., Neumann, B., Rose, U., Behring Inst. Mitt. Nr.55, 119 (1974).

    Google Scholar 

  19. Beau, J. M., Sinay, P., Kamerling, J. P., Vliegenthart, J. F. G., Carbohyd. Res.67, 65 (1978);

    Google Scholar 

  20. Beau, J. M., Schauer, R., Eur. J. Biochem.106, 531 (1980).

    Google Scholar 

  21. Brossmer, R., Rose, U., Kasper, D., Smith, T. L., Grasmuck, H., Unger, F. M., Biochem. Biophys. Res. Comm.1980, 1282.

  22. Zilliken, F., O'Brien, P. J., Biochem. Prep.7, 1 (1960);

    Google Scholar 

  23. Kuhn, R., Lutz, P., MacDonald, D. L., Chem. Ber.99, 611 (1966).

    Google Scholar 

  24. Guthrie, R. D., Jenkens, I. A., Yamasaki, R., Carbohyd. Res.85, C5-C6 (1980);

    Google Scholar 

  25. Chem. Comm.1980, 544;

  26. Mengel, R., Bartke, M., Angew. Chem.90, 725 (1978), Int. Ed.17, 679 (1978).

    Google Scholar 

  27. Brandstetter, H. H., Zbiral, E., Schulz, G., Ann. Chem., im Druck.

  28. Germain, G., Main, P., Woolfson, M. M., Acta Cryst.A 27, 368 (1971).

    Google Scholar 

  29. Die folgenden Computer-Programme fanden Verwendung: XRAY (Stewart, G. M., Technical Report TR-466, Computer Science Center, University of Maryland, USA), SHELX (Sheldrick, G. M., University of Cambridge, England).

Download references

Author information

Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Graz, A-8010, Graz, Österreich

    Christoph Kratky

  2. Institut für Organische Chemie, Universität Wien, A-1090, Wien, Österreich

    Hannelore H. Brandstetter & Erich Zbiral

Authors
  1. Christoph Kratky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hannelore H. Brandstetter
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Erich Zbiral
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kratky, C., Brandstetter, H.H. & Zbiral, E. Röntgenstrukturanalyse des Methyl-5-acetylamino-7,8-anhydro-4,9-bis-O-(t-butyldimethylsilyl)-3,5-didesoxy-L-glycero-β-D-galakto-2-nonulopyranosidon-säuremethylesters. Monatshefte für Chemie 112, 1105–1111 (1981). https://doi.org/10.1007/BF00905464

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00905464

Keywords

Search

Navigation