Reaction of esters of hypophosphorous acid with bis(diethylamino)methane and diethylaminomethyl ethyl ether

  • B. E. Ivanov
  • L. A. Kudryavtseva
Organic and Biological Chemistry

Conclusions

  1. 1.

    A study was made of the reaction of alkyl hypophosphites with bis(diethylamino)methane and diethylaminomethyl ethyl ether. A number of esters of bis(α-aminomethyl)phosphonic acids was obtained.

     
  2. 2.

    Bis(α-aminomethyl)phosphonic acids are obtained in the case of the alkyl hypophosphites where the alkyl radical contains more than 6 C atoms. The alkyl hypophosphites with smaller radicals give either the esters ofα-aminomethylphosphonic acids or a mixture of the latter with the esters of bis (α-aminomethyl)phosphonic acids.

     

Keywords

Ether Ester Methane Ethyl Small Radical 

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • B. E. Ivanov
    • 1
  • L. A. Kudryavtseva
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryAcademy of Sciences of the USSRUSSR

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