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Reaction of esters of hypophosphorous acid with bis(diethylamino)methane and diethylaminomethyl ethyl ether

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reaction of alkyl hypophosphites with bis(diethylamino)methane and diethylaminomethyl ethyl ether. A number of esters of bis(α-aminomethyl)phosphonic acids was obtained.

  2. 2.

    Bis(α-aminomethyl)phosphonic acids are obtained in the case of the alkyl hypophosphites where the alkyl radical contains more than 6 C atoms. The alkyl hypophosphites with smaller radicals give either the esters ofα-aminomethylphosphonic acids or a mixture of the latter with the esters of bis (α-aminomethyl)phosphonic acids.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1498–1501, July, 1967.

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Ivanov, B.E., Kudryavtseva, L.A. Reaction of esters of hypophosphorous acid with bis(diethylamino)methane and diethylaminomethyl ethyl ether. Russ Chem Bull 16, 1447–1449 (1967). https://doi.org/10.1007/BF00905347

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  • DOI: https://doi.org/10.1007/BF00905347

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