Reaction of peroxide radicals with CoII acetylacetonate

  • V. P. Shcheredin
  • E. T. Denisov
Physical Chemistry


  1. 1.

    The reaction of styrene peroxide radicals with CoII acetylacetonate was studied in the system chlorobenzene-styrene-azoisobutyronitrile-oxygen; the reaction proceeds bimolecularly with a constant k=2.9·109 exp (−7800/RT) mole−1· sec−1.

  2. 2.

    The rate constant of the reaction of the radicals formed from azoisobutyronitrile in chlorobenzene in the presence of oxygen, with CoII acetylacetonate was measured; k=2.3·104 mole−1· sec−1 (74°).



Oxygen Peroxide Styrene Acetylacetonate Chlorobenzene 
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Literature cited

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • V. P. Shcheredin
    • 1
  • E. T. Denisov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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