Reaction of peroxide radicals with CoII acetylacetonate

  • V. P. Shcheredin
  • E. T. Denisov
Physical Chemistry
  • 17 Downloads

Conclusions

  1. 1.

    The reaction of styrene peroxide radicals with CoII acetylacetonate was studied in the system chlorobenzene-styrene-azoisobutyronitrile-oxygen; the reaction proceeds bimolecularly with a constant k=2.9·109 exp (−7800/RT) mole−1· sec−1.

     
  2. 2.

    The rate constant of the reaction of the radicals formed from azoisobutyronitrile in chlorobenzene in the presence of oxygen, with CoII acetylacetonate was measured; k=2.3·104 mole−1· sec−1 (74°).

     

Keywords

Oxygen Peroxide Styrene Acetylacetonate Chlorobenzene 

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Literature cited

  1. 1.
    E. T. Denisov and N. M. Émanuél, Zh. Fiz. Khimii,30, 2499 (1956).Google Scholar
  2. 2.
    N. M. Émanuél, E. T. Denisov, and Z. K. Maizus, Chain Reactions of Oxidation of Hydrocarbons in the Liquid Phase [in Russian], “Nauka,” (1965).Google Scholar
  3. 3.
    E. T. Denisov, Zh. Fiz. Khimii,32, 1269 (1958).Google Scholar
  4. 4.
    I. P. Skibida, Z. K. Maizus, and N. M. Emanuél, Dokl. AN SSSR,167, 1105 (1966).Google Scholar
  5. 5.
    V. M. Gol'dberg, Dissertation [in Russian], Moscow (1965).Google Scholar
  6. 6.
    M. Talat-Erben and N. Onol Canad, J. Chem.,38, 1154 (1960).Google Scholar
  7. 7.
    R. F. Vasil'ev, O. N., Karpukhin and V. Ya. Shlyapintokh, Dokl. AN SSSR,125, 106 (1958).Google Scholar
  8. 8.
    J. A. Howard and K. U. Ingold, Canad. J. Chem.43, 2729, 2732 (1965).Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • V. P. Shcheredin
    • 1
  • E. T. Denisov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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