Complexes of decaborane with trialkyl-, triaryl-, trialkyltrithiophosphites and trialkyl-, trialkyltrithioarsenites

  • V. I. Stanko
  • A. I. Klimova
  • L. I. Zakharkin
Brief Communications

Summary

  1. 1.

    Decaborane forms complexes with triethylphosphite, triphenylphosphite, and dibutyl ester of phenylphosphinous acid, and triethyltrithiophosphite, the complexes being of the type: B10H12 [P(OR)3]2 and B10H12 [P(SR)3]2.

     
  2. 2.

    Triethyiarsenite, triethyltrithioarsenite, and tri(thioethyl)stibine are reduced by decaborane to the corresponding metals.

     

Keywords

Ester Form Complex Dibutyl Triethylphosphite Triphenylphosphite 

Literature cited

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    L. I. Zakharkin and V. I. Stanko, Izv. AN SSSR, Otd. khim. n., 1961, 2078.Google Scholar

Copyright information

© Consultants Bureau 1963

Authors and Affiliations

  • V. I. Stanko
    • 1
  • A. I. Klimova
    • 1
  • L. I. Zakharkin
    • 1
  1. 1.Heteroorganic Compounds InstituteAcademy of Sciences USSRUSSR

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