Free-radical addition of primary alcohols to unsaturated alcohols

  • G. I. Nikishin
  • V. D. Vorob'ev
Organic and Biological Chemistry
  • 21 Downloads

Summary

  1. 1.

    Reaction, initiated by t-butyl peroxide, between normal primary alcohols and unsaturated alcohols with the double bond in the allyl position leads to 1,4-alkanediols.

     
  2. 2.

    At molar proportions of saturated alcohol: allyl alcohol: peroxide of 20:1: 0.2–0.3, a reaction time of six hours, and a temperature of 160–170° the yields of 1∶1 adducts range from 50 to 60%.

     

Keywords

Alcohol Peroxide Reaction Time Adduct Double Bond 

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Copyright information

© Consultants Bureau 1963

Authors and Affiliations

  • G. I. Nikishin
    • 1
  • V. D. Vorob'ev
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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