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Synthesis of γ-organosilyl derivatives of propylphosphonic bichloride and diethyl ester

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Summary

  1. 1.

    The addition of hydride silanes to allylphosphonic dichloride and diethyl ester in presence of chlorplatinic acid or t-butyl peroxide proceeds in accordance with Farmer's rule.

  2. 2.

    It was shown to be possible to prepare 3-(alkylethoxysilyl)propylphosphonic ethyl esters by the Arbuzov reaction in yields of 45–80%.

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Literature cited

  1. E. F. Bugerenko, E. A. Chernyshev and A D. Petrov, Dokl. AN SSSR143, No. 4 (1962).

  2. E. H. Farmer, J. Soc. Chem. Ind.66, 86 (1947).

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  3. Yu. P. Egorov and E. D. Lubuzh. Dokl. AN SSSR136, 342 (1961).

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  4. L. Z. Soborovskii, Yu. M. Zinov'ev and L. I. Muler, Dokl. AN SSSR109, 98 (1956).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    E. A. Chernyshev, E. F. Bugerenko, E. D. Lubuzh & A. D. Petrov

Authors
  1. E. A. Chernyshev
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  2. E. F. Bugerenko
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  3. E. D. Lubuzh
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  4. A. D. Petrov
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Chernyshev, E.A., Bugerenko, E.F., Lubuzh, E.D. et al. Synthesis of γ-organosilyl derivatives of propylphosphonic bichloride and diethyl ester. Russ Chem Bull 11, 937–940 (1962). https://doi.org/10.1007/BF00905209

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  • DOI: https://doi.org/10.1007/BF00905209

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