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Orientation in the addition of some aluminum hydrides to 1,3-butadiene

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Lithium aluminum hydride and diethylaluminum hydride add to 1,3-butadiene both in the 1,2- (and 3,4-) position and the 1,4-position.

  2. 2.

    Aluminum hydride adds to 1,3-butadiene in the 1,2- (and 3,4-) position.

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Literature cited

  1. H. C. Brown, J. Amer. Chem. Soc.81, 5832 (1959).

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  2. R. Köster, Angew. Chem.71, 520 (1959).

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  3. M. F. Hawthorne, J. Amer. Chem. Soc.83, 2541 (1961).

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  4. K. Ziegler, in the book “Organometallic Chemistry,” (N. Y., 1960), pp. 234–235.

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Zakharkin, L.I., Savina, L.A. & Antipin, L.M. Orientation in the addition of some aluminum hydrides to 1,3-butadiene. Russ Chem Bull 11, 931–933 (1962). https://doi.org/10.1007/BF00905207

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  • DOI: https://doi.org/10.1007/BF00905207

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