Quantitative relation between the induction constants of substituent radicals and the physical chemical properties of nitro compounds

  • V. I. Slovetskii
  • A. A. Fainzil'berg
  • S. S. Novikov
Inorganic and Analytical Chemistry
  • 21 Downloads

Summary

  1. 1.

    The changes in the physical chemical properties studied in the series of nitroalkanes and their halogen derivatives is to a large degree determined by the induction constants of the substituent radicals.

     
  2. 2.

    With compounds of this series a quantitative relation was found between the induction constants of the substituent radicals, o*, and the spectroscopic characteristics, the dissociation constants, and the half-wave potentials in polarographic reduction.

     

Keywords

Physical Chemical Chemical Property Halogen Dissociation Constant Large Degree 

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Copyright information

© Consultants Bureau Enterprises, Inc. 1963

Authors and Affiliations

  • V. I. Slovetskii
    • 1
  • A. A. Fainzil'berg
    • 1
  • S. S. Novikov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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