Sodium and potassium pervanadates

  • N. K. Grigor'eva
  • K. N. Dergacheva
Inorganic and Analytical Chemistry


  1. 1.

    By fusing V2O5 with NaOH and KOH we have synthesized sodium perorthovanadate (Na3VO8) and potassium perpyrovanadate (K4V2O11) and studied some of their properties.

  2. 2.

    The individuality of the compounds has been confirmed by differential thermal analysis and qualitative x-ray phase analysis. Both compounds have high thermal stability, and begin to decompose above 110°. They are fairly stable in air at room temperatures.



Sodium Potassium Thermal Stability Thermal Analysis Differential Thermal Analysis 
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Literature cited

  1. 1.
    I. Meyer, A. Pawletta, Z. angew. Chem.39, 1284 (1926).Google Scholar
  2. 2.
    I. Meyer, A. Pawletta, Z. Phys. Chem.125, 49 (1927).Google Scholar
  3. 3.
    M. E. Rumpf, Compt. rend.200, 317 (1935).Google Scholar
  4. 4.
    M. E. Rumpf, Ann. chimie8, 456 (1937).Google Scholar
  5. 5.
    A. K. Babko and A. I. Volkova, Zh. obshch. khimii22 (84), 1108 (1952).Google Scholar
  6. 6.
    P. Souchay, F. Chauveau, Cotnpt. rend.245, 1434 (1957).Google Scholar
  7. 7.
    F. Chauveau, Bull. Soc. chim. France, No. 5, 819 (1960).Google Scholar
  8. 8.
    G. Kakabadse, N. I. Wilson, Nature,180, 861 (1937).Google Scholar
  9. 9.
    G. Kakabadse, H. J. Wilson, J. Chem. Soc. 2475 (1960).Google Scholar
  10. 10.
    A. Scheuer, Z. anorgan. Chem.16, 284 (1898).Google Scholar
  11. 11.
    P. G. Melikov and L. V. Pisarzhevskii, Investigations into Peroxides [in Russian], S. P., 1900.Google Scholar
  12. 12.
    L. V. Pisarzhevskii, Selected Works [in Russian]. Izd. AN USSR (Kiev, 1936).Google Scholar
  13. 13.
    P. G. Melikov and E. Elchaninov, Ber.42, 2291 (1909).Google Scholar
  14. 14.
    J. Beltrán, R. Trujillo, An. Real. soc. esp. fis. y quim.B47, 705 (1951).Google Scholar
  15. 15.
    J. Beltrát, Rodrigues Rios, An. Real. soc. esp. fis. y quim.B48, 388 (1952).Google Scholar
  16. 16.
    J. Beltrán, A. Castarto, F. Castarto, An. Real. soc. esp. fis. y quim.B52, 105 (1956).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1963

Authors and Affiliations

  • N. K. Grigor'eva
    • 1
  • K. N. Dergacheva
    • 1
  1. 1.N. S. Khurnakov Institute of General and Inorganic ChemistryAcademy of SciencesUSSR

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