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Reaction of nitrogen tetroxide and pentoxide with ozone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of gaseous N2O4 with ozonized oxygen in a 1∶2 molar ratio gives a 99.3% yield of N2 O5.

  2. 2.

    In the reaction of solid N2O5 at −78°, or N2O5 dissolved in CCl4 at −10°, with ozone the composition of N2O5 is unaltered.

  3. 3.

    We have determined for the first time the solubility of N2O5 in CCl4 in the range −10 to +19°. The solubility increases with the temperature and reaches 45.5% at 19°C.

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Literature cited

  1. Gmelins Handbuch der anorganischen Chemie, Berlin, Verlag Chemie (1936), SN, 4, Lief. 3, 837.

  2. E. Brinner and E. Perrotet, Helv. chim. acta,22, 585 (1939).

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  3. A. Chretien, M. Servigne, and F. Mahieux, Bull. Soc. chim. France, 49 (1960).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    S. Z. Makarov, T. I. Arnol'd & I. I. Vol'nov

Authors
  1. S. Z. Makarov
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  2. T. I. Arnol'd
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  3. I. I. Vol'nov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2156–2157, September, 1968.

Deceased.

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Makarov, S.Z., Arnol'd, T.I. & Vol'nov, I.I. Reaction of nitrogen tetroxide and pentoxide with ozone. Russ Chem Bull 17, 2051 (1968). https://doi.org/10.1007/BF00905023

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  • DOI: https://doi.org/10.1007/BF00905023

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