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The synthesis of heterocyclic compounds containing the cyclopentadienylmanganesetricarbonyl group as a substituent

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    4-(2-Methyloxazolyl)-, 4-(2-methylthiazolyl)-, and 2-indolylcyclopentadienylmanganesetricarbonyl were synthesized fromα-bromoacetylcyclopentadienylmanganesetricarbonyl.

  2. 2.

    All three heterocyclic substituents, judging from the NMR and IR spectra, are electron-acceptors in comparison to cyclopentadienylmanganesetricarbonyl.

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Literature cited

  1. A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and I. B. Zlotina, Izv. AN SSSR, Ser. Khim., 898 (1968).

  2. R. Elderfield (editor), Heterocyclic Compounds [Russian translation], Vol. 5, IL (1961), p. 247.

  3. A. Bischler and P. Fireman, Ber.,26, 1336 (1893).

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  4. A. R. Katritskii (editor), Physical Methods in the Chemistry of Heterocyclic Compounds [Russian translation], “Khimiya” (1966), p. 515.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2127–2128, September, 1968.

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Nesmeyanov, A.N., Zlotina, I.B., Kolobova, N.E. et al. The synthesis of heterocyclic compounds containing the cyclopentadienylmanganesetricarbonyl group as a substituent. Russ Chem Bull 17, 2017–2018 (1968). https://doi.org/10.1007/BF00905008

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  • DOI: https://doi.org/10.1007/BF00905008

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