Conclusions
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1.
The synthesis of polymethylenepolyphosphine compounds was accomplished by the condensation of the esters of trivalent phosphorus acids with the oxides of tertiary bis- and tris(chloromethyl)phosphines and the esters of bis(chloromethyl)phosphinic acid.
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2.
The metalation of pentaphenyldimethylenetriphosphine trioxide gave the potassium derivatives, the anions of which have a mesomeric structure, with a distribution of the charge between the oxygen and carbon atoms of the methine groups.
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3.
Phenyldistyrylphosphine oxide and diphenylphosphinic acid are formed when the dipotassium derivative of pentaphenyldimethylenetriphosphine trioxide is reacted with benzaldehyde.
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Literature cited
T. Ya. Medved, B. A. Korolev, K. S. Yudina, B. I. Stepanov, and M. I. Kabachnik, Teor. i Eksperim. Khim., AN UkrSSR,4, 116 (1968).
M. I. Kabachnik, K. B. Yatsimirskii, T. Ya. Medved, Z. A. Sheka, Yu. M. Polikarpov, and E. I. Sinyavskaya, DAN SSSR,171, 619 (1966).
V. N. Setkina, T. Ya. Medved, and M. I. Kabachnik, Izv. AN SSSR, Ser. Khim.,1967, 1399.
M. I. Kabachnik, T. Ya. Medved, and E. I. Matrosov, DAN SSSR,162, 339 (1965).
L. Maier, Helv. Chim. Acta,48, 1034 (1965).
K. A. Petrov, V. A. Parshina, and A. F. Manuilov, ZhOKh,35, 1602 (1965).
J. J. Richard and C. V. Banks, J. Org. Chem.,28, 123 (1963).
J. J. Richard, K. E. Burke, J. W. O'Laughlin, and C. V. Banks, J. Am. Chem. Soc.,83, 1722 (1961).
J. A. Cade, J. Chem. Soc.,1959, 2266.
G. Schwarzenbach and J. Zurc, Monatsh. Chem.,81, 202 (1950).
M. I. Kabachnik and T. Ya. Medved, Izv. AN SSSR, Otd. Khim. Nauk,1962, 2103.
K. S. Yudina, T. Ya. Medved, and M. I. Kabachnik, Izv. AN SSSR, Ser. Khim.,1966, 591.
M. I. Kabachnik, T. Ya. Medved, Yu. M. Polikarpov, and K. S. Yudina, Izv. AN SSSR, Ser. Khim.,1967, 1954.
H. G. Henning and G. Petzold, Z. Chem.,5, 419 (1965).
J. P. King, B. P. Block, and I. C. Popoff, Inorg. Chem.,4, 198 (1965).
V. E. Bel'skii, T. A. Zyablikova, A. R. Panteleeva, and I. M. Shermergorn, DAN SSSR,177, 340 (1967).
E. I. Matrosov, ZhSKh,6, 832 (1965).
H. Normant and G. Sturtz, Compt. Rend.,260, No. 7, 1984 (1965).
A. Ya. Yakubovich and P. A. Yufa, ZhOKh,28, 2853 (1958).
M. I. Kabachnik, E. N. Tsvetkov, and R. A. Malevannaya, Authors' certificate No. 170972; Byull. Izobr., No. 10, 28 (1965).
K. Moedritzer, J. Am. Chem. Soc.,83, 4381 (1961).
A. Hoffman, J. Am. Chem. Soc.,52, 2995 (1930).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.9, pp. 2062–2070, September, 1968.
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Medved, T.Y., Polikarpov, Y.M., Pisareva, S.A. et al. Phosphine oxides and phosphorus acids, containing several=P(O)CH2 groups in the molecule. Russ Chem Bull 17, 1959–1965 (1968). https://doi.org/10.1007/BF00904992
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DOI: https://doi.org/10.1007/BF00904992