Conclusions
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1.
We prepared some deuterated triphenylphosphines, containing deuterium in the o-, m-, and p-positions of one or all three phenyl rings, and also the oxides of some of them. The starting o-, m-, and p-deuterohalobenzenes were synthesized from the dihalobenzenes by the decomposition of the appropriate Grignard reagents with an excess of heavy water.
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2.
Some diphenyl-m-p-tolylphosphines, deuterated in the methyl group, and their oxides, were synthesized.
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3.
Methyldiphenylphosphine, containing deuterium in the methyl group, and some deuterated triphenyl-amines were prepared.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2050–2057, September, 1968.
We wish to thank A. I. Serebryanskaya for supplying the tri(o,o',p-trideuterophenyl)amine.
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Lobanov, D.I., Tsvetkov, E.N., Saltanova, E.V. et al. Synthesis of some deuterated tertiary arylphosphines and their oxides. Russ Chem Bull 17, 1949–1954 (1968). https://doi.org/10.1007/BF00904990
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DOI: https://doi.org/10.1007/BF00904990