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Investigation of the three-dimensional structure of 3,4-dibromocaranes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dipole moments and Kerr molar constants were measured at infinite dilution for two isomers of 3, 4-dibromocarane.

  2. 2.

    On the basis of a consideration of the Kerr constants and dipole moments found and calculated, as well as the calculated energy characteristics of the possible structures, conclusions were drawn on the configurations and conformation of the molecules of the investigated compounds.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, A. N. Vereshchagin & S. G. Vul'fson

Authors
  1. B. A. Arbuzov
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  2. A. N. Vereshchagin
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  3. S. G. Vul'fson
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1969–1974, September, 1968.

The authors would like to thank Z. G. Isaeva and I. B. Nemirovskaya for providing the preparation of the liquid isomer of dibromocarane.

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Arbuzov, B.A., Vereshchagin, A.N. & Vul'fson, S.G. Investigation of the three-dimensional structure of 3,4-dibromocaranes. Russ Chem Bull 17, 1878–1881 (1968). https://doi.org/10.1007/BF00904975

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  • DOI: https://doi.org/10.1007/BF00904975

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