Conclusions
-
1.
On the basis of the data obtained for nonsymmetrical phenyl derivatives of mercury, it was hypothesized that the ionic character of the C-Hg bond increases in the series C6H5HgBr ≈ C6H5HgCl < C6H5HgOAc < C6H5HgNO3.
-
2.
In the study of the PMR spectrum of 2,4, 6-trideuterophenylmercury chloride we determined the values of\(\delta _{{\rm H}_m } \) and\(J_{{\rm H}_m - {\rm H}_g ^{199} } \).
-
3.
An investigation of the PMR spectra of substituted phenyl derivatives of mercury indicated that the influence of the substituents on the spectral parameters is in good agreement with the modern concepts of the electronic properties of the substituents.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
I. P. Beletskaya, A. E. Myshkin, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 240 (1965); 238, 245 (1967).
R. D. Brown, A. S. Buchanan, and A. A. Humffray, Austral. J. Chem.,18, 1507 (1965).
O. Itoh, H. Taniguchi, A. Kawabe, and K. Ichikawa, J. Chem. Soc. Japan,69, 913 (1966).
V. I. Pakhomov, Zh. Strukt. Khim.,4, 594 (1963);5, 873 (1964).
C. Curran, J. Amer. Chem. Soc.,64, 830 (1942).
J. C. Sipos, H. Sawatzky, and G. F. Wright, J. Amer. Chem. Soc.,77, 2759 (1955).
G. Leandri and A. Tundo, J. Chem. Soc., 3377 (1954).
B. G. Gowenlock and J. Trotman, J. Chem. Soc., 1454 (1955).
V. Baliah and P. Subbarayan, J. Indian. Chem. Soc.,40, 638 (1963).
G. E. Coates and D. Ridley, J. Chem. Soc., 166 (1964).
J. W. Hatton, W. G. Schneider, and W. Siebrand, J. Chem. Phys.,39, 1330 (1963).
N. S. Ham, E. A. Jeffry, T. Mole, and S. N. Stuart, Chem. Comm.,6, 254 (1967).
G. M. Ostapchuk, Dissertation [in Russian], Moscow (1958).
V. S. Petrosyan and O. A. Reutov, Dokl. Akad. Nauk SSSR,180, 876 (1968).
J. A. Ladd, Spectrochim. Acta,22, 1157 (1966).
V. S. Petrosyan and O. A. Reutov, Zh. Organ. Khim.,3, 2074 (1967).
G. W. Smith, J. Molec. Spectr.,12, 146 (1964).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1962–1966, September, 1968.
In conclusion, the authors would like to express their gratitude to B. P. Bespalov and A. L. Kurts for heir aid in the experimental work.
Rights and permissions
About this article
Cite this article
Petrosyan, V.S., Reutov, O.A. Proton magnetic resonance spectra of phenyl derivatives of mercury. Russ Chem Bull 17, 1871–1874 (1968). https://doi.org/10.1007/BF00904973
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00904973