Summary
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1.
In the alkylation of tetralin with normal pyropyl, butyl, heptyl, nonyl, and decyl bromides in presence of aluminum at 23°, 65°, and 105° the corresponding propyl-, butyl-, heptyl-, nonyl-, and decyl-tetralins are formed in yields of 53–99%.
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2.
Conditions were found under which the alkylation of tetralin proceeds without the isomerization of the substituents.
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V. D. Azatyan, Dokl. AN SSSR59, 901 (1948).
M. B. Turova-Polyak and N. P. Dobrosel'skaya, Zh. obshch. khimii29, 1072 (1959).
B. N. Dolgov and S. A. Bnatov, Zh. obshch. khimii29, 582 (1959).
N. G. Sidorova, I. P. Tsukervanik and Z. Kh. Avidova, Dokl. AN Uz. SSSR5, 53 (1953).
N. I. Shuikin, B. L. Lebedev, and N. A. Pozdnyak, Neftekhimiya1, 39 (1961).
B. N. Dolgov and S. A. Bnatov, Izv. vysshikh uch. zavedenii5, 714 (1959).
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Shuikin, N.I., Pozdnyak, N.A. & Lifanova, I.N. Catalytic alkylation of tetralin. Russ Chem Bull 11, 643–645 (1962). https://doi.org/10.1007/BF00904768
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DOI: https://doi.org/10.1007/BF00904768