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Hexafluoroacetone in the wittig reaction

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    4,4-Bistrifluoromethyl-3-buten-2-one was prepared by the reaction of hexafluoroacetone with acetonyl-idenetriphenylphosphorane.

  2. 2.

    1,1-Bistrifluoromethyl-1,3-butadiene was synthesized by the reduction of 4,4-bistrifluoromethyl-3-buten-2-one with subsequent dehydration of the resulting alcohol.

  3. 3.

    Ammonia adds to 4,4-bistrifluoromethyl-3-buten-2-one with formation of the α-amino ketone.

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Authors and Affiliations

  1. Institute of HeteroorganicCompounds, Academy of Sciences, USSR

    V. F. Plakhova & N. P. Gambaryan

Authors
  1. V. F. Plakhova
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  2. N. P. Gambaryan
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Plakhova, V.F., Gambaryan, N.P. Hexafluoroacetone in the wittig reaction. Russ Chem Bull 11, 630–632 (1962). https://doi.org/10.1007/BF00904765

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  • DOI: https://doi.org/10.1007/BF00904765

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