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Action of lead tetraacetate on 3-carene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In the course of the action of lead tetraacetate on 3-carene the acetate of the same (+)-alcohol is formed as was found in the products of the autoxidation of 3-carene.

  2. 2.

    The alcohol under investigation is identical to the product of the oxidation of 3-carene with SeO2, but is not a compound of the carene series.

  3. 3.

    In the autoxidation of 3-carene in presence of Pb(OCOCH3)2 there is formed not only eucarvone, but also a second ketone having a seven-membered ring, namely 3,6,6-trimethyl-2,4-cycloheptadien-1-one.

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Literature cited

  1. B. A. Arbuzov, Z. G. Isaeva, and V. V. Ratner, Dokl. AN SSSR 134, 583 (1960).

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, V. I. Ul'yanov-LeninKazan' University, USSR

    B. A. Arbuzov, Z. G. Isaeva & V. V. Ratner

Authors
  1. B. A. Arbuzov
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  2. Z. G. Isaeva
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  3. V. V. Ratner
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Arbuzov, B.A., Isaeva, Z.G. & Ratner, V.V. Action of lead tetraacetate on 3-carene. Russ Chem Bull 11, 594–598 (1962). https://doi.org/10.1007/BF00904759

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  • DOI: https://doi.org/10.1007/BF00904759

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