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Methylation and periodate oxidation of clematosides A', A, and B

  • V. Ya. Chirva
  • A. N. Usov
  • V. P. Konyukhov
Organic and Biological Chemistry
  • 16 Downloads

Conclusions

  1. 1.

    The methylated monosaccharides formed in the methylation of clematosides A′, A, and B have been separated and identified by gas-liquid chromatography.

     
  2. 2.

    The preparative isolation of the methylated monosaccharides has been carried out and their structures have been confirmed by chemical methods.

     
  3. 3.

    The structure of clematosides A′, A, and B has been discussed in the light of the results of methylation and periodate oxidation.

     

Keywords

Oxidation Methylation Chromatography Chemical Method Monosaccharide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    V. Ya. Chirva and V. P. Konyukhov, Khimiya Prirodnykh Soedinenii, No. 2, 140 (1968).Google Scholar
  2. 2.
    V. Ya. Chirva and V. P. Konyukhov, Khimiya Prirodnykh Soedinenii, No. 2, 141 (1968).Google Scholar
  3. 3.
    A. J. Khorlin, V. J. Chirva, and N. K. Kochetkov, Tetrahedron Letters,1965, 2201.Google Scholar
  4. 4.
    A. Ya. Khorlin, V. Ya. Chirva, and N. K. Kochetkov, Izv. AN SSSR, Ser. Khim.,1966, 1963.Google Scholar
  5. 5.
    C. T. Bishop, Advances Carbohydr. Chenu,19, 95 (1964).Google Scholar
  6. 6.
    G. O. Aspinall, J. Chem. Soc.,1965, 1676.Google Scholar
  7. 7.
    J. Honeyman, J. Chem. Soc.,1940, 990.Google Scholar
  8. 8.
    J. T. Edward and D. M. Waldron, J. Chem. Soc.,1952, 3631.Google Scholar
  9. 9.
    J. K. N. Jones and J. H. S. Thomas, Can. J. Chem.,39, 192 (1961).Google Scholar
  10. 10.
    J. R. Dyer, Methods Biochem. Anal.,3, 111 (1954).Google Scholar

Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • V. Ya. Chirva
    • 1
    • 2
  • A. N. Usov
    • 1
    • 2
  • V. P. Konyukhov
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.Institute of ChemistryAcademy of Sciences of the Moldavian SSRUSSR

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