Radiolysis of aqueous solutions of potassium hydroxylaminedisulfonate

  • V. A. Sharpatyi
  • N. V. Zakatova
Physical Chemistry

Conclusions

  1. 1.

    The radiolysis of aqueous solutions of potassium hydroxylaminedisulfonate under various conditions of irradiation (concentration, pH, introduction of additives, etc.) was studied by the EPR method.

     
  2. 2.

    The results obtained indicate a radiolytic oxidation of HON(SO3K)2 by OH radicals.

     
  3. 3.

    The high conversion yields of HON(SO3K)2 dissolved in water are treated on the basis of the concept of the participation of the conversion products of excited water molecules in the reactions.

     
  4. 4.

    The system HON(SO2K)3 + H2O can be recommended as an indicator system for determining the rate constant of the reaction of the oxidative component of the radiolysis of water with dissolved substances.

     

Keywords

Oxidation Potassium Aqueous Solution Water Molecule High Conversion 

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Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • V. A. Sharpatyi
    • 1
  • N. V. Zakatova
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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