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Radiolysis of aqueous solutions of potassium hydroxylaminedisulfonate

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The radiolysis of aqueous solutions of potassium hydroxylaminedisulfonate under various conditions of irradiation (concentration, pH, introduction of additives, etc.) was studied by the EPR method.

  2. 2.

    The results obtained indicate a radiolytic oxidation of HON(SO3K)2 by OH radicals.

  3. 3.

    The high conversion yields of HON(SO3K)2 dissolved in water are treated on the basis of the concept of the participation of the conversion products of excited water molecules in the reactions.

  4. 4.

    The system HON(SO2K)3 + H2O can be recommended as an indicator system for determining the rate constant of the reaction of the oxidative component of the radiolysis of water with dissolved substances.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    V. A. Sharpatyi & N. V. Zakatova

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  1. V. A. Sharpatyi
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  2. N. V. Zakatova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2197–2203, October, 1968.

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Sharpatyi, V.A., Zakatova, N.V. Radiolysis of aqueous solutions of potassium hydroxylaminedisulfonate. Russ Chem Bull 17, 2082–2086 (1968). https://doi.org/10.1007/BF00904019

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  • DOI: https://doi.org/10.1007/BF00904019

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