Abstract
Complexes of lanthanide nitrates with 2-methylpyridine-1-oxide of the formuleLn(2-MePyO)3(NO3)3 whereLn=Nd, Sm, Tb, Dy and Yb and La(2-MePyO)3(NO3)3·2H2O have been prepared and characterized by chemical analyses, IR spectral, conductance andDTA data. IR spectral data have been interpreted in terms of the coordination of the ligand to the metal through the oxygen of the N−O group. Conductance and IR spectral data show that all the nitrate groups are bidentate and that two of the nitrate groups are bound to the metal in a different manner than the other.
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Literatur
G. A. Pneumaticakis, Chem. and Ind. [London],1968, 770.
V. Boekelheide undW. J. Linn, J. Amer. Chem. Soc.76, 1286 (1954).
J. A. Riddick undW. B. Bunger, Techniques of Chemistry, Vol. II, Organic Solvents, New York: Wiley-Interscience. 1970.
A. I. Vogel, A text-book of Quantitative Inorganic Analysis, 3. Aufl., S. 583. London: The English Language Book Society and Longmans. 1962.
H. H. Willard, L. L. Merrit, Jr., undJ. A. Dean, Instrumental Methods of Analysis, 4. Aufl., S. 89. New Delhi: Affiliated East-West Press Pvt. Ltd. 1965.
N. F. Curtis undY. M. Curtis, Inorg. Chem.4, 804 (1965).
C. C. Addison, N. Logan, S. C. Wallwork undC. D. Garner, Quart. Rev. Chem. Soc.25, 289 (1971).
A. B. P. Lever, E. Mantovani undB. S. Ramaswamy, Canad. J. Chem.49, 1957 (1971).
R. J. Foster undD. G. Hendriker, Inorg. Chim. Acta6, 371 (1972).
J. R. Ferraro, C. Cristallini undI. Fox, J. Inorg. Nucl. Chem.29, 139 (1967).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, S. 167, New York, Wiley-Interscience. 1970.
W. J. Geary, Coord. Chem. Rev.7, 81 (1971).
S. K. Ramalingam undS. Soundararajan, J. Inorg. Nucl. Chem.29, 1763 (1967).
S. S. Krishnamurthy undS. Soundararajan, J. Less-common Metals13, 619 (1967).
K. K. Bhandary undH. Manohar, Acta Crystallogr.29 (B), 1093 (1973).
K. K. Bhandary, H. Manohar undK. Venkatesan, Cryst. Structure Commun.2, 99 (1973).
K. K. Bhandary, H. Manohar undK. Venkatesan, J. Chem. Soc. Dalton Trans.1975, 288.
K. K. Bhandary, Ph. D. Thesis, Indian Institute of Science, 1973.
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Ramakrishnan, L., Soundararajan, S. Komplexe von Lanthanidnitraten mit 2-Methylpyridin-1-oxid. Monatshefte für Chemie 107, 1095–1101 (1976). https://doi.org/10.1007/BF00903796
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DOI: https://doi.org/10.1007/BF00903796