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Monatshefte für Chemie / Chemical Monthly

, Volume 110, Issue 1, pp 121–127 | Cite as

Reaktionen von (E)-Cycloocten mitN-Bromsuccinimid in Gegenwart von Wasser oder Methanol

  • Günter Haufe
Organische Chemie und Biochemie

Reactions of (E)-cyclooctene with N-bromosuccinimide in the presence of water, and methanol, resp. Transanular reactions of cycloalkenes, cycloalkadienes and cycloalkatrienes, VII Transanulare Reaktionen von Cycloalkenen, Cycloalkadienen und Cycloalkatrienen, 7. Mitt.

Abstract

The reactions of (E)-cyclooctene withN-bromosuccinimide in the presence of water or methanol are described. Major products of the hydroxybromination aretrans-4-bromocyclooctanol as a product of intermediary transanular hydride migration, and two ring contracted bromohydrines. The methoxybromination has been found to occur similarly.

Keywords

E-Cyclooctene Hydride migration Transanular migration 

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Copyright information

© Springer-Verlag 1979

Authors and Affiliations

  • Günter Haufe
    • 1
  1. 1.Sektion ChemieKarl-Marx-Universität LeipzigLeipzigDeutsche Demokratische Republik

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