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Tetracyclic triterpenes. Part 5. The synthesis of epimeric 9,11-epoxides in the tri-, hexa-, and octa-norlanostane series

Tetrazyklische Triterpene. 5. Mitt. Synthese von epimeren 9,11-Epoxiden in der Tri-, Hexa-, und Octa-Norlanostan-Reihe (Kurze Mitteilung)

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  • Organische Chemie und Biochemie
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Abstract

Lanosterol was converted by degradation of the side chain followed by transformations within rings B and C into a series of 9,11-epoxy-7-oxo-4,4,14α-trimethylsteroids.

Zusammenfassung

Lanosterin wurde durch Abbau der Seitenkette und nachfolgende Transformationen innerhalb der Ringe B und C in die 9,11-Epoxy-7-oxo-4,4,14α-trimethylsteroidreihe umgewandelt.

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References

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Part IV.Paryzek, Z., Wydra, R., Bull. Acad. Polon. Sci., Ser. sci. chim.26, 591 (1978).

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Paryzek, Z., Wydra, R. Tetracyclic triterpenes. Part 5. The synthesis of epimeric 9,11-epoxides in the tri-, hexa-, and octa-norlanostane series. Monatshefte für Chemie 111, 1427–1431 (1980). https://doi.org/10.1007/BF00903668

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  • DOI: https://doi.org/10.1007/BF00903668

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