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Funktionelle Derivate von Polynitroverbindungen

  • Organische Chemie und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Zusammenfassung

DieMichael-Kondensation des 2-Nitro-3-acetoxy-1-propens1 ermöglichte die Darstellung neuer aliphatischer Polynitroverbindungen mit zusätzlichen funktionellen Gruppen. Von besonderem Interesse sind die Verbindungen mit dreigem-Dinitrogruppen in der Kette, die durch direkte Nitrierung derAci-Salze von Kondensationsprodukten des 2-Nitro-3-acetoxy-1-propens mitgem-Dinitroverbindungen erhalten wurden.

Die Reaktionsbedingungen wurden ermittelt und die Struktur der neuen Verbindungen sichergestellt.

Abstract

The study of reaction products from 2-nitro-3-acetoxy-1-propene1 byMichael reactions led to the preparation of new aliphatic polynitro compounds containing functional groups. Of particular interest are compounds containing threegem-dinitro groups in a chain that have been obtained by direct nitration of theaci-salts of the condensation products from 2-nitro-3-acetoxy-1-propene withgem-dinitrocompounds. The reaction conditions have been established and the structure of the new compounds elucidated.

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Authors and Affiliations

  1. Forschungslaboratorium der Aerojet General Corporation, Sacramento, Kalifornien, USA

    K. Klager & M. B. Frankel

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  1. K. Klager
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  2. M. B. Frankel
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Herrn Professor Dr.Fritz Wessely zum 70. Geburtstag in dankbarer Verehrung gewidmet.

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Klager, K., Frankel, M.B. Funktionelle Derivate von Polynitroverbindungen. Monatshefte für Chemie 99, 1336–1350 (1968). https://doi.org/10.1007/BF00902677

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  • DOI: https://doi.org/10.1007/BF00902677

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