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Die Kristallstruktur der monoklinen Form von As2O3 (Claudetit II)

The crystal structure of the monoclinic form ofAs 2O3(claudetite II)

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Claudetite II crystallizes monoclinic (a 0=7.99,b 0=4.65,c 0=9.12 Å, β=78.3°;Z=4) with space group P21/n-C 52h . AnR-factor of 0.07 was obtained from 568 observed independent reflections using individual anisotropic temperature factors. Each of the two crystallographically different As-atoms forms a flat trigonal pyramid with three oxygens. The pyramids are connected in two dimensions by common corners to form undulating sheets parallel to (001).

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Literatur

  1. E. Kürbs, K. Plieth undI. N. Stranski, Z. anorg. Chem.258, 238 (1949).

    Google Scholar 

  2. K. A. Becker, K. Plieth undI. N. Stranski, Z. anorg. allgem. Chemie266, 293 (1951).

    Google Scholar 

  3. K. A. Becker, K. Plieth undI. N. Stranski, Z. anorg. allgem. Chemie275, 297 (1954).

    Google Scholar 

  4. K. A. Becker, K. Plieth undI. N. Stranski, Prog. Inorg. Chem. Vol.4 (F. A. Cotton, Hrsg.). New York-London: J. Wiley. 1962.

    Google Scholar 

  5. W. Wahler, N. Jb. Min., Abh.101, 109 (1964).

    Google Scholar 

  6. K. A. Becker, H. Karge undI. N. Stranski, Z. physik. Chem.44, 1 (1965).

    Google Scholar 

  7. K. Mereiter, Unveröffentlichtes Computer-Programm (1973).

  8. C. T. Prewitt, Unveröffentlichtes Computer-Programm (1964).

  9. K. E. Almin undA. Westgren, Ark. Kemi, Min. Geol.,15 B, No. 22, 1 (1942).

    Google Scholar 

  10. A. J. Frueh, Amer. Min.36, 833 (1951).

    Google Scholar 

  11. K. A. Becker, K. Plieth undI. N. Stranski, Z. anorg. allgem. Chemie269, 92 (1952).

    Google Scholar 

  12. A. F. Wells, Structural Inorganic Chemistry, 3. Aufl. Oxford: Clarendon Press. 1962.

    Google Scholar 

  13. N. Morimoto, Min. Journ. [Japan]1, 160 (1954).

    Google Scholar 

  14. D. J. E. Mullen undW. Nowacki, Z. Krist.136, 48 (1972).

    Google Scholar 

  15. I. Karutz undI. N. Stranski, Z. anorg. allgem. Chemie292, 330 (1957).

    Google Scholar 

  16. Z. Galdecki, Roczniki Chem.30, 355 (1956).

    Google Scholar 

  17. Z. Galdecki undE. Jozefowicz, Łodz. Towarz. Nauk Wydzial III, Acta Chim.9, 5 (1964).

    Google Scholar 

  18. M. Edstrand undG. Blomqvist, Ark. Kemi8, 245 (1955).

    Google Scholar 

  19. K. A. Becker, J. Block undH. Saure, Ber. Bunsenges. phys. Chem.75, 406 (1971).

    Google Scholar 

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Pertlik, F. Die Kristallstruktur der monoklinen Form von As2O3 (Claudetit II). Monatshefte für Chemie 106, 755–762 (1975). https://doi.org/10.1007/BF00902181

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  • DOI: https://doi.org/10.1007/BF00902181

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