Abstract
Claudetite II crystallizes monoclinic (a 0=7.99,b 0=4.65,c 0=9.12 Å, β=78.3°;Z=4) with space group P21/n-C 52h . AnR-factor of 0.07 was obtained from 568 observed independent reflections using individual anisotropic temperature factors. Each of the two crystallographically different As-atoms forms a flat trigonal pyramid with three oxygens. The pyramids are connected in two dimensions by common corners to form undulating sheets parallel to (001).
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Literatur
E. Kürbs, K. Plieth undI. N. Stranski, Z. anorg. Chem.258, 238 (1949).
K. A. Becker, K. Plieth undI. N. Stranski, Z. anorg. allgem. Chemie266, 293 (1951).
K. A. Becker, K. Plieth undI. N. Stranski, Z. anorg. allgem. Chemie275, 297 (1954).
K. A. Becker, K. Plieth undI. N. Stranski, Prog. Inorg. Chem. Vol.4 (F. A. Cotton, Hrsg.). New York-London: J. Wiley. 1962.
W. Wahler, N. Jb. Min., Abh.101, 109 (1964).
K. A. Becker, H. Karge undI. N. Stranski, Z. physik. Chem.44, 1 (1965).
K. Mereiter, Unveröffentlichtes Computer-Programm (1973).
C. T. Prewitt, Unveröffentlichtes Computer-Programm (1964).
K. E. Almin undA. Westgren, Ark. Kemi, Min. Geol.,15 B, No. 22, 1 (1942).
A. J. Frueh, Amer. Min.36, 833 (1951).
K. A. Becker, K. Plieth undI. N. Stranski, Z. anorg. allgem. Chemie269, 92 (1952).
A. F. Wells, Structural Inorganic Chemistry, 3. Aufl. Oxford: Clarendon Press. 1962.
N. Morimoto, Min. Journ. [Japan]1, 160 (1954).
D. J. E. Mullen undW. Nowacki, Z. Krist.136, 48 (1972).
I. Karutz undI. N. Stranski, Z. anorg. allgem. Chemie292, 330 (1957).
Z. Galdecki, Roczniki Chem.30, 355 (1956).
Z. Galdecki undE. Jozefowicz, Łodz. Towarz. Nauk Wydzial III, Acta Chim.9, 5 (1964).
M. Edstrand undG. Blomqvist, Ark. Kemi8, 245 (1955).
K. A. Becker, J. Block undH. Saure, Ber. Bunsenges. phys. Chem.75, 406 (1971).
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Pertlik, F. Die Kristallstruktur der monoklinen Form von As2O3 (Claudetit II). Monatshefte für Chemie 106, 755–762 (1975). https://doi.org/10.1007/BF00902181
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DOI: https://doi.org/10.1007/BF00902181