Skip to main content
SpringerLink
Log in

Magnetische Eigenschaften der ternären Phase (Co x Ni1−x )11Se8

Magnetic properties of the ternary phase (Co x Ni1−x )11Se8

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The composition range of the ternary body-centered tetragonal phase (Co x Ni1−x )11Se8 extends fromx=0.03 tox=0.37 at 580°C. The magnetic susceptibilities and their variation with temperature and composition were investigated within the temperature range from 100 to 300 K using a magnetic balance. The temperature dependence of the magnetic suceptibilities was found to be consistent with theCurie-Weiss law from which magnetic moments were derived. Assuming the magnetic moments as spin-only values each cobalt atom contributes two unpaired electrons. Change in composition did not affect the magnitude of the magnetic moments. Based on crystallographic and magnetic data a simple model for the mutual distribution of cobalt and nickel atoms could be constructed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. E. Røst undK. Haugsten, Acta Chem. Scand.23, 388 (1969).

    Google Scholar 

  2. E. Røst undK. Haugsten, Acta Chem. Scand.23, 1601 (1969).

    Google Scholar 

  3. H. Haraldsen, R. Møllerud undE. Røst, Acta Chem. Scand.21, 1727 (1967).

    Google Scholar 

  4. P. Terzieff, Mh. Chem.107, 289 (1976).

    Google Scholar 

  5. K. L. Komarek, E. Reiffenstein undP. Terzieff, Mh. Chem.105, 957 (1974).

    Google Scholar 

  6. K. L. Komarek undP. Terzieff, Mh. Chem.106, 145 (1975).

    Google Scholar 

  7. E. Vandenbempt, L. Pauwels undK. De Clippeleir, Bull. Soc. Chim. Belges80, 283 (1971).

    Google Scholar 

  8. F. Bøhm, F. Grønvold, H. Haraldsen undH. Prydz, Acta Chem. Scand.9, 1510 (1955).

    Google Scholar 

  9. H. Haraldsen, F. Grønvold undT. Hurlen, Z. anorg. allgem. Chem.283, 143 (1955).

    Google Scholar 

  10. W. Klemm, Z. anorg. allgem. Chem.246, 347 (1941).

    Google Scholar 

  11. W. R. Angus, Proc. Roy. Soc. A136, 569 (1932).

    Google Scholar 

  12. K. L. Komarek undK. Wessely, Mh. Chem.103, 923 (1972).

    Google Scholar 

  13. A. L. N. Stevels, J. Bouwma, G. A. Wiegers undF. Jellinek, Rec. Trav. Chim. Pays-Bas87, 705 (1968).

    Google Scholar 

  14. A. L. N. Stevels, Diss. Groningen, Philips Res. Rep., Suppl. 9 (1969).

  15. A. L. N. Stevels, J. Bouwma, G. A. Wiegers undF. Jellinek, Rec. Trav. Chim. Pays-Bas84, 1585 (1968).

    Google Scholar 

  16. F. Grønvold undE. Jacobsen, Acta Chem. Scand.10, 1440 (1956).

    Google Scholar 

  17. P. W. Anderson, Phys. Rev.124, 41 (1961).

    Google Scholar 

  18. A. Clogston, B. Matthias, M. Peter, H. Williams, E. Corenzwit undSherwood, Phys. Rev.125, 541 (1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Wien, Währinger Straße 42, A-1090, Wien, Österreich

    Peter Terzieff

Authors
  1. Peter Terzieff
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Mit 3 Abbildungen

Rights and permissions

Reprints and permissions

About this article

Cite this article

Terzieff, P. Magnetische Eigenschaften der ternären Phase (Co x Ni1−x )11Se8 . Monatshefte für Chemie 108, 451–457 (1977). https://doi.org/10.1007/BF00902000

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00902000

Search

Navigation