Monatshefte für Chemie / Chemical Monthly

, Volume 108, Issue 2, pp 361–366 | Cite as

Polarographic studies of indium(III) complexes with some disubstituted pyridines

  • R. S. Sindhu
  • K. B. Pandeya
  • R. P. Singh
Anorganische, Struktur- und Physikalische Chemie

Abstract

Complex formation of indium(III) with three disubstituted pyridines, viz., 2,3-dihydroxypyridine, 2-amino-3-hydroxypyridine and 3-hydroxypyridine-2-thiol has been studied polarographically (μ=0.1; temp.=25±0.1°C). All the systems show reversible electrode behaviour.DeFord andHume method as modified byIrving has been applied for determining composition and stability constants. Distribution of different species as a function of ligand concentration has been calculated and shown graphically.

Keywords

Indium Physical Chemistry Analytical Chemistry Inorganic Chemistry Organic Chemistry 

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References

  1. 1.
    D. Cozzi andS. Vivarelli, Z. Elektrochem.58, 907 (1954).Google Scholar
  2. 2.
    P. C. Rawat andC. M. Gupta, Talanta19, 706 (1972).Google Scholar
  3. 3.
    A. V. Pandeya andM. L. Mittal, J. Inorg. Nucl. Chem.34, 2365 (1972).Google Scholar
  4. 4.
    L. Treindl, Rev. Chim. Miner.5, 397 (1968).Google Scholar
  5. 5.
    J. J. Savič andI. Filipovič, Croat. Chem. Acta37, 91 (1965).Google Scholar
  6. 6.
    V. F. Toropova, G. K. Budnikov, V. N. Maistrenko, andI. V. Nagorskova, J. Gen. Chem. of U.S.S.R.43, 2117 (1973).Google Scholar
  7. 7.
    Ya. I. Tur'yan andN. K. Strizhov, Russ. J. Inorg. Chem.17, 1066 (1972).Google Scholar
  8. 8.
    R. S. Saxena andU. S. Chaturvedi, J. Inorg. Nucl. Chem.34, 3272 (1972).Google Scholar
  9. 9.
    J. N. Gaur, D. S. Jain, andM. M. Palrecha, J. Chem. Soc.A 1968, 2201.Google Scholar
  10. 10.
    J. N. Gaur, R. C. Mehrotra, M. M. Palrecha, D. S. Jain, Anand Kumar, andC. M. Gupta, J. Polarogr. Soc.14, 122 (1968).Google Scholar
  11. 11.
    Veena Kushwaha, M. Katyal, andR. P. Singh, Talanta21, 763 (1974).Google Scholar
  12. 12.
    D. D. DeFord andD. N. Hume, J. Amer. Chem. Soc.73, 5321 (1951).Google Scholar
  13. 13.
    H. Irving, Advances in polarography1, 42 (1960).Google Scholar
  14. 14.
    Y. I. Turyan andN. L. Bondarenko, Zh. neorg. Khim.4, 1070 (1959).Google Scholar

Copyright information

© Springer-Verlag 1977

Authors and Affiliations

  • R. S. Sindhu
    • 1
  • K. B. Pandeya
    • 1
  • R. P. Singh
    • 1
  1. 1.Department of ChemistryUniversity of DelhiDelhiIndia

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